What hormone is responsible for the expression of secondary sexual characteristics in human females?

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Estrogen

The secondary sexual characteristics in human females include development of breast, widening of hips, increase in body fat and growth of genital hairs. A diagram follows :

The effect of estrogen in body : Here, we can see estrogen is responsible for all the secondary female sexual characteristics. Here is a small diagram showing the effect of estrogen on female (and testosterone on male):

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